Oxidative Addition of Carbon–Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex
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چکیده
منابع مشابه
Four-electron oxidative formation of aryl diazenes using a tantalum redox-active ligand complex.
Transition-metal complexes capable of mediating multielectron transformations are critical components for a variety of small-molecule transformations. For example, the oxidation of C H bonds and the reduction of protons to H2 are both two-electron transformations. The oxidation of water to O2 is a four-electron process and the reduction of nitrogen to ammonia is an overall six-electron process....
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2012
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja306526d